This work highlights the conversion method of chaining up greenhouse gas CO2 with biomass lignin to develop new sustainable, recyclable polymers from abundant and non-food based renewable resources. A cyclic carbonate monomer has synthesized using a cost-effective, non-phosgene-based, and greener approach under atmospheric pressure and room temperature. The fully programable ring-opening polymerization is accomplished by varying the catalyst (DBU and TBD), catalyst loading (0.5–5.0%) and reaction time (2–40 min). The best polymer is obtained in 1% TBD with a 30-min reaction. The precise characterization of the synthesized cyclic carbonate monomer and polymers' structure are established using spectroscopic analyses including 1H, 13C, and 2D HSQC NMR, FT-IR, and GPC. The new polymers exhibit high molecular weights (Mn: 120.34–154.58 kDa) and adequate thermal stabilities (Td5%: 244–277 °C from TGA and Tg: 33–52 °C from DSC), rendering them advantageous for practical applications. Significantly, the CO2 and lignin-based polymers have successfully recycled to the monomer for a circular plastic economy by heating at 90 °C for 12 h in the presence of DBU. This process yields original monomers for another polymerization without unwanted changes in chemical structures, presenting an ultimate sustainable solution.
CITATION STYLE
Ghorai, A., & Chung, H. (2024). CO2 and Lignin-Based Sustainable Polymers with Closed-Loop Chemical Recycling. Advanced Functional Materials. https://doi.org/10.1002/adfm.202403035
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