Abstract
Single crystals of the title compound, tetra-lutetium(III) tris-(cyclo-tetra-phosphate), Lu4(P4O12) 3, were obtained by solid-state reaction. The cubic structure is isotypic with its AlIII and ScIII analogues and is built up from four-membered (P4O12)4- phosphate ring anions ( ̄ 4 symmetry), isolated from each other and further linked through isolated LuO6 octa-hedra (.3. symmetry) via corner sharing. Each LuO6 octa-hedron is linked to six (P4O12)4- rings, while each (P4O12)4- ring is linked to eight LuO6 octa-hedra.
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CITATION STYLE
Mbarek, A., Fourati, M., Zambon, D., & Avignant, D. (2010). Lutetium(III) cyclotetraphosphate. Acta Crystallographica Section E: Structure Reports Online, 66(6). https://doi.org/10.1107/S1600536810016363
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