Controlled dye release from a metal-organic framework: A new luminescent sensor for water

Abstract

By introducing the dye Rhodamine 6G (R6G) into a metal-organic framework (MOF), Mn-sdc-2 (H2sdc = 4,4′-stilbenedicarboxylic acid), with a pore size of 20 × 9.8 Å2, the composite R6G@Mn-sdc-2 was obtained. Subsequently, the MOF Mn-sdc-1 with a smaller pore size of 7.5 × 7.5 Å2 can be formed through a single-crystal to single-crystal transformation from Mn-sdc-2, thus tightly locking the dye R6G within the pores. Compared with R6G@Mn-sdc-2, R6G@Mn-sdc-1 exhibits a stronger fluorescence emission of R6G. Because the MOF Mn-sdc-1 can reversibly transform back to Mn-sdc-2 in the presence of trace water, the dye R6G can be released. This enables R6G@Mn-sdc-1 to be used as a new luminescent sensor for trace water in organic solvents by monitoring the fluorescence intensity of released R6G. The limit of detection can reach 0.035% in ethanol (v:v), which is among the most sensitive fluorescent water probes.