Hexaethylguanidinium salts

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Abstract

Crystal structures of five hexaethylguanidinium salts (PF6− 1, FeCl4− 2, CuCl42−·H2O 3, CoBr42−/Br−·H2O 4, bistriflimide 5) were determined. Short interionic contacts were identified. Cyclic voltammetry of 2 revealed an electrochemical window from +1.0 to −1.5 V with a single Fe(III)/Fe(II) redox event at −0.27 V on a gold electrode versus Ag/AgCl.

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Salchner, R., Kahlenberg, V., Gelbrich, T., Wurst, K., Rauch, M., Laus, G., & Schottenberger, H. (2014). Hexaethylguanidinium salts. Crystals, 4(3), 404–416. https://doi.org/10.3390/cryst4030404

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