Anion-induced self-assembly of positively charged polycyclic aromatic hydrocarbons towards nanostructures with controllable two-dimensional morphologies

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Abstract

A controllable self-assembly strategy of positively charged polycyclic aromatic hydrocarbons (PCPAH) towards the formation of rectangle sheets and ribbon-like nanostructures has been achieved by choosing divalent anions with different sizes. In contrast, only rod-like nanostructures are obtained from PCPAH with univalent anions. It is revealed that the divalent anions play a key role in guiding the packing of PCPAH, which provides an unprecedented route to fabricate two-dimensional nanostructures.

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Yang, C., Wu, D., Zhao, W., Ye, W., Xu, Z., Zhang, F., & Feng, X. (2016). Anion-induced self-assembly of positively charged polycyclic aromatic hydrocarbons towards nanostructures with controllable two-dimensional morphologies. CrystEngComm, 18(6), 877–880. https://doi.org/10.1039/c5ce02171e

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