Comparison of dynamic light scattering and rheometrical methods to determine the gel point of a radically polymerized hydrogel under mechanical shear

Abstract

The phase transition of nanocomposite hydrogels made of N-isopropylacrylamide (NIPAm) and clay (Laponite® XLS) was investigated under mechanical shear influencing the gelation. The hydrogels were synthesized by free radical polymerization. For the processing of cross-linked gels, the phase transition (liquid-solid) and its dependence on mechanical stress are of paramount importance. On the one hand, the determination of the gel point (tg) is possible with rheometry and, on the other hand, with dynamic light scattering (DLS). With rotational rheometry, by identifying the abrupt increase of viscosity, the gel point is evaluated. The DSL is an alternative method to rheometry, to investigate hydrogels under the action of the shear flow, to make results comparable to the rheometric investigations, with and without shear. Experimental parameters were chosen based on preparatory work to obtain comparable results regarding the determination of the gel point of a radically polymerized NIPAm hydrogel.