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Semisynthesis of cis- and trans-solamin by acidic opening of natural diepomuricanin A - A mechanistic investigation

European Journal of Organic Chemistry (2001) (16) 3161-3164
DOI: 10.1002/1099-0690(200108)2001:16<3161::AID-EJOC3161>3.0.CO;2-U
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Abstract

MS/MS spectroscopy allowed us to determine the mechanism of the acidic opening of diepomuricanin A, by analysis of the product distribution after treatment with H218O in the presence of HClO4 in anhydrous acetone.

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Gleye, C., Franck, X., Hocquemiller, R., Laurens, A., Laprévote, O., De Barros, S., & Figadère, B. (2001). Semisynthesis of cis- and trans-solamin by acidic opening of natural diepomuricanin A - A mechanistic investigation. European Journal of Organic Chemistry, (16), 3161–3164. https://doi.org/10.1002/1099-0690(200108)2001:16<3161::AID-EJOC3161>3.0.CO;2-U

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