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Highly enantioselective catalytic fluorination and chlorination reactions of carbonyl compounds capable of two-point binding

Angewandte Chemie - International Edition (2005) 44(27) 4204-4207
DOI: 10.1002/anie.200501041
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Abstract

(Chemical Equation Presented) New tools in drug development: The catalytic enantioselective fluorination and chlorination reactions of carbonyl compounds containing an additional binding site (see scheme) proceed with extremely high enantioselectivity and require low catalyst loadings (2-10 mol% dbfox-Ph/ NiII). Asymmetric amplification is also observed in these enantioselective halogenations. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

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Shibata, N., Kohno, J., Takai, K., Ishimaru, T., Nakamura, S., Toru, T., & Kanemasa, S. (2005). Highly enantioselective catalytic fluorination and chlorination reactions of carbonyl compounds capable of two-point binding. Angewandte Chemie - International Edition, 44(27), 4204–4207. https://doi.org/10.1002/anie.200501041

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