Compression speed as a parameter changing the dimensionality of corrole nanostructures in layers at the air-water interface

Abstract

An influence of compression speed of a layer on the structure and properties of stable floating layers of 5,10,15-triphe-nylcorrol was investigated. Model of face-on monolayers with an increased (by 30 % compared to the quasi-stationary) compression rate has been constructed by method of quantitative analysis of isotherms. It was shown that an increase in the compression speed leads to an increase in the density of both two-dimensional nanoaggregates formed in the layer and the monolayer itself. In addition, there was a significant shift in the boundaries of the existence of floating mono and multilayers in the direction of smaller values of the initial degree of surface coverage.