Abstract
Femtosecond UV-VIS and mid-IR experiments show that a new class of biomimetic photoswitches photo-isomerizes in less than 300 fs. In close analogy to rhodopsin, the isomerization is driven by ultrafast motion along the stretch and the torsional coordinates.
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Briand, J., Sharma, D., Léonard, J., Helbing, J., Cannizzo, A., Chergui, M., … Olivucci, M. (2009). Ultrafast Isomerization Dynamics of Biomimetic Photoswitches. In Springer Series in Chemical Physics (Vol. 92, pp. 343–345). Springer Science and Business Media Deutschland GmbH. https://doi.org/10.1007/978-3-540-95946-5_111
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