Energy dissipation bounds for autonomous thermodynamic cycles

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Abstract

How much free energy is irreversibly lost during a thermodynamic process? For deterministic protocols, lower bounds on energy dissipation arise from the thermodynamic friction associated with pushing a system out of equilibrium in finite time. Recent work has also bounded the cost of precisely moving a single degree of freedom. Using stochastic thermodynamics, we compute the total energy cost of an autonomously controlled system by considering both thermodynamic friction and the entropic cost of precisely directing a single control parameter. Our result suggests a challenge to the usual understanding of the adiabatic limit: Here, even infinitely slow protocols are energetically irreversible.

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Bryant, S. J., & Machta, B. B. (2020). Energy dissipation bounds for autonomous thermodynamic cycles. Proceedings of the National Academy of Sciences of the United States of America, 117(7), 3478–3483. https://doi.org/10.1073/pnas.1915676117

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