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Insights into: D 4h@metal-symmetry single-molecule magnetism: The case of a dysprosium-bis(boryloxide) complex

Chemical Communications (2021) 57(6) 733-736
DOI: 10.1039/d0cc07446b
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Abstract

We report the synthesis of the lanthanide-(bis)boryloxide complex [Dy{OB(NArCH)2}2(THF)4][BPh4] (2Dy, Ar = 2,6-Pri2C6H3), with idealised D4h@Dy(iii) point-group symmetry. Complex 2Dy exhibits single-molecule magnetism (SMM), with one of the highest energy barriers (Ueff = 1565(298) K) of any six-coordinate lanthanide-SMM. Complex 2Dy validates electrostatic model predictions, informing the future design of lanthanide-SMMs. This journal is

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CITATION STYLE

APA

Thomas-Hargreaves, L. R., Hunger, D., Kern, M., Wooles, A. J., Van Slageren, J., Chilton, N. F., & Liddle, S. T. (2021). Insights into: D 4h@metal-symmetry single-molecule magnetism: The case of a dysprosium-bis(boryloxide) complex. Chemical Communications, 57(6), 733–736. https://doi.org/10.1039/d0cc07446b

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