Nowadays biosource-based materials have received revitalized interest for their ability to substitute for petrochemical-based materials. In this paper, we report a facile synthetic method of soybean oil-based polyfunctional acrylate (PFA) for UV-curable materials. Specifically, rapid and highly efficient side-chain functionalization of soybean oil was achieved via photoclick thiol-ene reaction, soybean oil-based polycarboxylic acid (PCA) was thus obtained. Next, by DCC (N,N′-dicyclohexylcarbodiimide) catalyzed esterification reaction with hydroxypropyl acrylate, polyfunctional acrylate (PFA) was synthesized at room temperature. Real-FTIR result indicated that almost 100% conversion of double-bond within vegetable oil was observed within 16.7 min, yielding the soybean oil-based polycarboxylic acid quantitatively. Furthermore, the structure of PFA was confirmed by1H NMR and FTIR. Finally, the excellent UV-curing rate of PFA was revealed by real-FTIR. © 2014 Elsevier B.V.
CITATION STYLE
Wegner, F. (2016). Supermathematics and its Applications in Statistical Physics. Progress in Organic Coatings (Vol. 920, pp. 868–871). Springer Berlin Heidelberg. Retrieved from http://link.springer.com/10.1007/978-3-662-49170-6
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