Synthesis of novel chiral diamino alcohols and their application in copper-catalyzed asymmetric allylic oxidation of cycloolefins

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Abstract

The small library of new enantiomerically pure (S,S)-diamino alcohols 1 and their hydroxyldiamide precursors 2 were conveniently synthesized on a gram scale from inexpensive and commercially chiral pool amino acids. The catalytic and induced asymmetric effects of the chiral ligands 1 in the asymmetric allylic oxidation of cycloolefins were investigated.

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APA

Faraji, L., Samadi, S., Jadidi, K., & Notash, B. (2014). Synthesis of novel chiral diamino alcohols and their application in copper-catalyzed asymmetric allylic oxidation of cycloolefins. Bulletin of the Korean Chemical Society, 35(7), 1989–1995. https://doi.org/10.5012/bkcs.2014.35.7.1989

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