Abstract
Gentle oxidation of lithium titanate spinel (LiTi2O4) with water at room temperature gives Li-deficient Li0.33Ti2O4. Combined X-ray and neutron Rietveld analysis shows that 28% of the Ti cations are displaced to alternative octahedral sites, in keeping with a proposed model based on Ti-migration limited by Li-vacancy concentration.
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CITATION STYLE
APA
Kitada, A., Arevalo-Lopez, A. M., & Attfield, J. P. (2015). Titanium migration driven by Li vacancies in Li1-xTi2O4 spinel. Chemical Communications, 51(57), 11359–11361. https://doi.org/10.1039/c5cc02800k
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