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A tris(carbene) pincer complex: Monomeric platinum carbonyl with three bound carbene centers

Angewandte Chemie - International Edition (2003) 42(34) 4054-4057
DOI: 10.1002/anie.200351320
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Abstract

Carbon monoxide replaces cod in the mono carbene phosphane imine complex 1 (see picture) to form, through a double silyl migration reaction, the remarkable complex 2 containing three carbene centers bound to platinum (cod = cycloocta-1,5-diene).

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Lin, G., Jones, N. D., Gossage, R. A., McDonald, R., & Cavell, R. G. (2003). A tris(carbene) pincer complex: Monomeric platinum carbonyl with three bound carbene centers. Angewandte Chemie - International Edition, 42(34), 4054–4057. https://doi.org/10.1002/anie.200351320

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