Natural Remediation Potential of Arsenic-Contaminated Ground Water

Abstract

Migration of leachate from a municipal landfill in Saco, Maine has resulted in arsenic concentrations in ground water as high as Laboratory experimental data indicate the primary source of arsenic to be reductive dissolution of arsenic-enriched iron oxyhydroxides in the aquifer by organic carbon in landfill leachate. A core from an uncontaminated part of the aquifer yielded no dissolved iron or arsenic when leached with oxic ground water. Eluent ground water spiked with organic carbon in order to create reducing conditions mobilized both ferrous iron and arsenite from this core. The landfill was capped in early 1998 to eliminate the source of leachate. Cores from the contaminated portion of the aquifer were collected and leached with uncontaminated ground water in the laboratory to simulate natural remediation conditions. Data from these experiments show that significant concentrations of labile organic carbon have accumulated on aquifer solids, causing significant biological oxygen demand. In laboratory leaching experiments of the most contaminated core, the organic carbon caused complete consumption of the influent dissolved oxygen (6 mg/L) for 220 pore volumes. Arsenic leaching from contaminated cores rapidly decreased in concentration initially in response to flushing with uncontaminated ground water. Subsequent leaching produced more gradual decreases in dissolved arsenic concentrations, controlled by a combination of reductive dissolution of arsenic-enriched iron oxyhydroxides and adsorption/desorption. In leachate from the most contaminated core, arsenic concentrations exceeded the new United States Environmental Protection Agency drinking-water standard of for more than 200 pore volumes. A geochemical model simulated the concentration of selected constituents as uncontaminated ground water eluted through contaminated aquifer solids. Concentrations of dissolved oxygen, arsenic, and iron, in leachate from one core were used to calibrate the model. This model was validated by successfully simulating constituent concentrations in leachate from cores collected from other contaminated areas of this aquifer. 352 Chapter 13 INTRODUCTION 1.