Synthesis of capped TiO2 nanocrystals of controlled shape and their use with MEH-PPV conjugated polymer to develop nanocomposite films for photovoltaic applications

Abstract

This study presents the synthesis details of titanium dioxide (TiO 2) nanoparticles (NPs) of different shapes (nanospheres, nanorods and nanorhombics) using oleic acid (OA) and oleyl amine (OM) as capping agents. In order to develop nanocomposite thin films for photovoltaic cells, these TiO 2 NPs were carefully dispersed in 2-methoxy-5-(2'-ethylhexyloxy)-p- phenylene vinylene (MEH-PPV) matrix. The properties of synthesized TiO 2 NPs and MEH-PPV/TiO2 nanocomposites were characterized using transmission electron microscopy (TEM), thermogravimetric analysis (TGA), UV-Visible spectroscopy, and Photoluminescence technique. It was found that the shape of NPs and the amount of OA and OM surfactants capped on their surface have an effect on their energy bandgap and also on the dispersion quality of MEH-PPV/TiO2 nanocomposites. Even though there was no evidence of chemical bonding between MEH-PPV matrix and TiO2 dispersed NPs, MEH-PPV/TiO2 nanocomposites showed very promising results for light absorption properties and charge transfer at the interface of the conjugated MEH-PPV matrix and TiO2 dispersed NPs, which are two main characteristics for photovoltaic materials. © 2014 American Institute of Physics.