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Infrared spectroscopic evidence for the formation of carbonite CO22- ions in CO interaction with basic oxide surfaces

Reaction Kinetics and Catalysis Letters (1987) 34(1) 9-14
DOI: 10.1007/BF02069193
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Abstract

Infrared studies of12C16O,13C16O and12C18O adsorption at 60-300 K on thermally activated CaO and MgO indicate that the CO interaction with O2- ions yields CO22- ions. These ions are the intermediates of more complex surface compounds and are responsible for the CO isotope exchange with surface oxygen. © 1987 Akadémiai Kiadó.

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Babaeva, M. A., & Tsyganenko, A. A. (1987). Infrared spectroscopic evidence for the formation of carbonite CO22- ions in CO interaction with basic oxide surfaces. Reaction Kinetics and Catalysis Letters, 34(1), 9–14. https://doi.org/10.1007/BF02069193

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