Innovative measurement methodology in quality assessment of coatings

Abstract

In the European project MANIAC-Innovative Measurement Methodology in Quality Assessment of Coating, a methodology was developed to assess the long term durability of coatings. The project was focused on environmentally friendly waterborne automotive multi-layer coating systems. Although developed for waterborne coatings, the methodology is very generic and can be applied to all kinds of coatings. The first step in the evaluation of long-term performance of automotive coatings involves exposures to weathering (natural as well as artificial). Traditionally, the durability of coatings is evaluated by examining the changes in performance properties like gloss, color, and scratch resistance. In the MANIAC methodology, the focus is on changes in structures on molecular levels. Microtomed slices of the coatings were examined by FTIR spectroscopy for monitoring oxidation. UV spectroscopy and GC-MS were used to study the migration of additives like HALS and UVA. In the methodology, the environmental variables (outdoors as well as indoors), e.g., temperature, relative humidity, UV irradiation, were carefully monitored and included in the modeling scheme. The results from accelerated tests are modeled and, together with outdoor climatic data, the different models are used to predict degradation during outdoor exposure. © Springer Science+Business Media, LLC 2009.