Dicaesium tetra-chlorido-dioxido-plutonate(VI)

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Abstract

The anion of the title complex, Cs2[PuCl4O2], adopts a pseudo-octa-hedral geometry (2/m crystallographic site symmetry) with two plutonyl oxide ligands in axial sites and four chloride ligands occupying the equatorial plane. Charge balance is maintained by two caesium cations per tetra-chlorido-dioxido- plutonate(VI) anion. Principal bond lengths include Pu - O = 1.752 (3) Å and Pu - Cl = 2.6648 (8) Å. © International Union of Crystallography 2008.

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Wilkerson, M. P., & Scott, B. L. (2008). Dicaesium tetra-chlorido-dioxido-plutonate(VI). Acta Crystallographica Section E: Structure Reports Online, 64(1). https://doi.org/10.1107/S1600536807066354

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