The estimation of corrosion behavior of NiTi and NiTiNb alloys using dynamic electrochemical impedance spectroscopy

Abstract

Linear anodic potentiodynamic polarization and dynamic electrochemical impedance spectroscopic (DEIS) measurements were carried out for NiTi and NiTiNb alloys in physiological 0.9 wt% NaCl solution in order to assess their corrosion resistance. DEIS measurements were performed from open circuit potential to dissolution potential. It was shown that the impedance measurements in potentiodynamic conditions allow simultaneous investigation of changes in passive layer structure. The impedance spectra of various potential regions were fitted and also discussed. The surface morphology of the alloys after linear anodic polarization test was studied using scanning electron microscopy (SEM) technique. © 2013 Georgiana Bolat et al.