Deposition process of sulfate and elemental carbon in japanese and thai forests

Abstract

Particulate matter deposited on leaf surfaces may cause erosion/abrasion of epicuticular wax and the malfunction of stomata. However, the deposition processes of particulate matter, such as elemental carbon (EC), has not been studied sufficiently in Asian forest ecosystems. Deposition processes for particulate SO42- and EC were studied in a Japanese cedar forest in Kajikawa, Niigata Prefecture, Japan, and in a dry evergreen forest and a dry deciduous forest in Sakaerat, Nakhon Ratchasima province, Thailand. The SO42- fluxes attributed to rainfall outside the forest canopy (RF), throughfall (TF), and stemflow (SF) showed distinct seasonalities at both sites, increasing from November to February at the Kajikawa site and in March/April at the Sakaerat site. Seasonal west/ northwest winds in winter may transport sulfur compounds across the Sea of Japan to the Kajikawa site. At the Sakaerat site, pollutants suspended in the air or dry deposits from the dry season might have been washed away by the first precipitations of the wet season. The EC fluxes from RF and TF showed similar variations by season at the Kajikawa site, while the flux from TF was frequently lower than that from RF at the Sakaerat site. Particulate matter strongly adsorbed onto leaf surfaces is not washed away by rainfall and contributes to the EC flux. At the Kajikawa site, Japanese cedar leaf surfaces accumulated the highest levels of particulate matter and could not be neglected when calculating the total flux. When such leaf-surface particles were considered, the contribution of dry deposition to the total EC flux was estimated to be 67%, 77%, and 82% at the Kajikawa site, and at the evergreen and deciduous forests of the Sakaerat site, respectively. Leaf-surface particles must be included when evaluating the dry and total fluxes of particulate matter, in particular for waterinsoluble constituents such as EC.