The chemical recycling of end-of-life plastic waste streams can contribute to a resource-conserving and sustainable society. This matter of recycling is composed of a sequence of depolymerization and subsequent polymerization reactions. In this regard, we have studied the chemical recycling of end-of-life poly(bisphenol A carbonate) applying phenol as depolymerization reagent. In the presence of catalytic amounts of alkali metal halides as products bisphenol A and diphenyl carbonate were obtained in excellent turnover frequencies of up to 1392 h−1 and short reaction times. These depolymerization products offer the straightforward possibility to close the cycle by producing new poly(bisphenol A carbonate) and as second product phenol, which can be reused for further depolymerizations.
CITATION STYLE
Alberti, C., Scheliga, F., & Enthaler, S. (2019). Recycling of End-of-Life Poly(bisphenol A carbonate) via Alkali Metal Halide-Catalyzed Phenolysis. ChemistryOpen, 8(7), 822–827. https://doi.org/10.1002/open.201900149
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