Highly porous activated carbons were synthesized via the mechanochemical salt-templating method using both sustainable precursors and sustainable chemical activators. Tannic acid is a polyphenolic compound derived from biomass, which, together with urea, can serve as a low-cost, environmentally friendly precursor for the preparation of efficient N-doped carbons. The use of various organic and inorganic salts as activating agents afforded carbons with diverse structural and physicochemical characteristics, e.g., their specific surface areas ranged from 1190 m2·g−1 to 3060 m2·g−1 . Coupling the salt-templating method and chemical activation with potassium oxalate appeared to be an efficient strategy for the synthesis of a highly porous carbon with a specific surface area of 3060 m2·g−1, a large total pore volume of 3.07 cm3·g−1 and high H2 and CO2 adsorption capacities of 13.2 mmol·g−1 at −196◦C and 4.7 mmol·g−1 at 0◦C, respectively. The most micro-porous carbon from the series exhibited a CO2 uptake capacity as high as 6.4 mmol·g−1 at 1 bar and 0◦C. Moreover, these samples showed exceptionally high thermal stability. Such activated carbons obtained from readily available sustainable precursors and activators are attractive for several applications in adsorption and catalysis.
CITATION STYLE
Głowniak, S., Szczęśniak, B., Choma, J., & Jaroniec, M. (2021). Highly porous carbons synthesized from tannic acid via a combined mechanochemical salt-templating and mild activation strategy. Molecules, 26(7). https://doi.org/10.3390/molecules26071826
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