The present work extends the family of nonconventional proton acceptors to the coinage metal Au. Based on high level computations, we demonstrate the ability of the triangle three-gold cluster to behave as nonconventional proton acceptor and hence to form hydrogen bonds with conventional hydrogen bond donors. Three molecules: formic acid, alanine, and adenine, involving O-H and N-H groups as typical conventional hydrogen bond donors, are chosen for this purpose.
CITATION STYLE
Kryachko, E. S., & Remacle, F. (2006). THREE-GOLD CLUSTER AS PROTON ACCEPTOR IN NONCONVENTIONAL HYDROGEN BONDS O-H…Au AND N-H…Au. In Progress in Theoretical Chemistry and Physics (Vol. 15, pp. 433–450). Springer Nature. https://doi.org/10.1007/1-4020-4528-X_21
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