Abstract
To and fro: Chiral metal-organic frameworks (CMOFs) derived from redox-active ruthenium/salen building blocks exhibited reversible single-crystal to single-crystal reduction and reoxidation. The catalytically inactive Ru III CMOFs (green; see picture) were reduced to Ru II CMOFs (red) that were highly active for the asymmetric cyclopropanation of alkenes with very high diastereo- and enantioselectivities. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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CITATION STYLE
Falkowski, J. M., Wang, C., Liu, S., & Lin, W. (2011). Actuation of asymmetric cyclopropanation catalysts: Reversible single-crystal to single-crystal reduction of metal-organic frameworks. Angewandte Chemie - International Edition, 50(37), 8674–8678. https://doi.org/10.1002/anie.201104086
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