Zn salts incorporated polyurethane/polyacrylonitrile electrospinning fiber membrane for high porosity polymer electrolyte in Zn ion battery

Abstract

So far, a large variety of polymer molecule architectures have been explored in the electrolyte field. Polymer electrolytes have gathered research efforts as an interesting alternative to conventional liquid electrolytes due to their advantages of low probability of leakage and low volatility of liquid solvent, lightweight, flexibility, inertness, high durability, and thermal stability. In this work, a polymer electrolyte developed from a polyurethane/polyacrylonitrile (PU/PAN) electrospinning fiber membrane was added with different zinc (Zn) salts, namely, Zn(CH3CO2)2, ZnSO4, and Zn(OTf)2. The samples with the Zn salt presented many different properties; especially, the high Zn(OTf)2 sample showed gradually bundle morphology in its structure. Characterization revealed improved properties in contact angle, water uptake, and thermal resistance. Namely, the 15 wt% Zn(OTf)2) sample exhibited an outstandingly high ionic conductivity of 3.671 mS cm−1, which is 10 times higher than that of the neat PU/PAN membrane.