Deteimination of Waterborne Bioavailable Organochlorine Pesticide Residues in the Lower Missouri River

Abstract

The semipermeable membrane device (SPMD) technology, developed and patented by the National Biological Service's (NBS) Midwest Science Center (MSC), was used to determine the presence of bioavailable organochlorine (OC) pesticides in the water of the main stem Missouri River. Specifically, the SPMDs were deployed for 28 days at five main stem sites-Sioux City, IA; Nebraska City, NE; Kansas City, MO (above metropolitan area); Glasgow, MO; and Hermann, MO. In general, OCs were present at all sites. Of all targeted analytes, the chlordane components, heptachlor expoxide, toxaphene, and dieldrin were generally present at the highest concentrations. For example, heptachlor epoxide ranged from a high of 180 ng/sample at Hermann to a low of 22 ng/sample at Sioux City, while dieldrin ranged from a high of 800 ng/sample at Glasgow to a low of 64 ng/sample at Sioux City. Replicate (n = 4) SPMD samplers sequestered similar quantities (typical CV = 10-35%) of each OC pesticide. The sequestered residues represent an estimation of bioavailable (by respiration process) or dissolved OCs present in the main stem of the Missouri River. © 1995, American Chemical Society. All rights reserved.