Fabrication of Composite Material with Pd Nanoparticles and Graphene on Nickel Foam for Its Excellent Electrocatalytic Performance

Abstract

Incorporation of precious metallic nanoparticles onto a carbon support material is used to obtain an electrocatalyst for ethanol oxidation. A composite material of spherical palladium nanoparticles (Pd NPs), reduced graphene oxide (rGO), and polydopamine (PDA) on three-dimensional nickel foam (NF) substrate (Pd/rGO/PDA@NF) has been synthesized for ethanol electrocatalysis. The Pd nanoparticles were obtained via reduction of precursor K2PdCl4 using ascorbic acid at 60 °C for 80 min. The rGO with large specific surface area was used in catalysts to provide large amounts of active sites for Pd NPs. Meanwhile, Pd NPs as an effective ingredient in catalyst exhibited excellent electrochemical activity of ethanol oxidation. Local surface plasmon resonance was carried out to determine the optimal concentration of precursor K2PdCl4 aqueous solution, and the absorbance peak of Pd NPs was found at about 340–370 nm by UV-visible spectroscopy. An enhanced property of the composite material Pd/rGO/PDA@NF was demonstrated to catalyze the ethanol oxidation reaction in alkaline electrolyte solution. A higher ratio of forward scan peak current intensity (If) to reverse scan peak current intensity (Ib) was 1.59, which demonstrated the significant anti-poison effect to carbonaceous intermediates of the Pd/rGO/PDA@NF. The value of If can maintain 90.6% after 400 cycles, indicating the higher cycling stability and better electrocatalytic performance toward ethanol oxidation. [Figure not available: see fulltext.].