Pilot Study on Fire Effluent Condensate from Full Scale Residential Fires

Abstract

Studies related to effluent produced by structure and vegetation fires often focus on gas phase or solid condensed phase, with limited treatment of liquid condensate generated as smoke cools to ambient. Recent post-fire human health concerns related to systemic human exposures to fire smoke and contamination of water distribution systems after wildland urban interface fires can be informed by understanding the chemical composition of liquid condensate resulting from large-scale fire experiments. In this pilot study, fire effluent (smoke) samples were continuously drawn from five different full-scale room-and-contents fire experiments, from which condensate was collected as the effluent cooled. Elevated concentrations of several volatile organic compounds (VOCs), including benzene, toluene, xylenes, styrene, naphthalene, and acetone along with several anions were detected in the acidic effluent. Many of these same VOCs have been identified in the air during firefighter safety experiments and in post-fire water distribution systems at levels that raise concern for human health. Benzene and naphthalene concentrations in the condensate were orders of magnitude above typical water quality standards and thus may directly contaminate large volumes of water. Peak benzene concentrations were similar to highest values reported from contaminated water distribution systems after wildfire events, though additional study is needed to understand the mechanisms by which this condensate may contribute to systemic contamination. Improved understanding of liquid condensate from fire effluent may be important to other areas of human and environmental health study, and some considerations are provided for future research.