Asymmetric radical alkylation of: N -sulfinimines under visible light photocatalytic conditions

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Abstract

In this communication, a new photocatalytic strategy for the addition of alkyl-radical derivatives to N-sulfinimines with complete diastereoselectivity and moderate to good yields is presented. This is the first asymmetric photocatalytic addition to N-sulfinimines under visible light irradiation with smooth conditions and functional group tolerance.

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Garrido-Castro, A. F., Choubane, H., Daaou, M., Maestro, M. C., & Alemán, J. (2017). Asymmetric radical alkylation of: N -sulfinimines under visible light photocatalytic conditions. Chemical Communications, 53(55), 7764–7767. https://doi.org/10.1039/c7cc03724d

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