Integrated plasmon-enhanced Raman scattering (iPERS) spectroscopy

Abstract

A new strategy named integrated plasmon-enhanced Raman scattering (iPERS) spectroscopy that features a configuration of evanescent field excitation and inverted collection is presented, which well unites the local field enhancement and far field emission, couples localized and propagating surface plasmons, integrates the SERS substrates and Raman spectrometers via a self-designed aplanatic solid immersion lens. A metallic nanoparticle-on-a film (NOF) system was adopted in this configuration because it improves the amplification of the incidence light field in near field by 10 orders of magnitude due to the simultaneous excitation of quadrupolar and dipolar resonance modes. This iPERS allows for higher excitation efficiency to probed molecules and full collection of the directional-radiation Raman scattering signal in an inverted way, which exhibits a practical possibility to monitor plasmonic photocatalytic reactions in nanoscale and a bright future on interfacial reaction studies.