Minisci reaction of heteroarenes and unactivated C(sp3)-H alkanes via a photogenerated chlorine radical

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Abstract

Here, an efficient Minisci reaction of heteroarenes and unactivated C(sp3)-H alkanes was achieved using an inexpensive FeCl3 as a photocatalyst. The photogenerated chlorine radical contributed to the HAT of C-H and subsequently initiated this reaction. Surprisingly, salt water and even seawater can act as a chlorine radical source, which provided an enlightening idea for future organic synthesis methods.

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APA

Pan, Z. T., Shen, L. M., Dagnaw, F. W., Zhong, J. J., Jian, J. X., & Tong, Q. X. (2023). Minisci reaction of heteroarenes and unactivated C(sp3)-H alkanes via a photogenerated chlorine radical. Chemical Communications, 59(12), 1637–1640. https://doi.org/10.1039/d2cc06486c

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