Gold-catalyzed synthesis of tetrazoles from alkynes by Cï£ ¿C bond cleavage

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Abstract

Golden duality: Tetrazoles are formed by the reaction of alkynes with TMSN3 (TMS=trimethylsilyl) in the presence of iPrOH and the gold(I) catalyst [JohnPhosAu(MeCN)]SbF6. In this transformation gold plays a dual role, first activating the alkyne and then generating a Brønsted acid in situ. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Gaydou, M., & Echavarren, A. M. (2013). Gold-catalyzed synthesis of tetrazoles from alkynes by Cï£ ¿C bond cleavage. Angewandte Chemie - International Edition, 52(50), 13468–13471. https://doi.org/10.1002/anie.201308076

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