Dichloridobis[3-(4-chlorophenyl)-2,N,N-trimethyl-2,3-dihydro-1,2, 4-oxadiazole-5-amine-κN 4]platinum(II)-4-chlorobenzaldehyde (1/1)

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Abstract

In the title 1:1 co-crystal, [PtCl2(C11H14ClN3O)2]·C7H5ClO, the coordination polyhedron of the PtII atom is slightly distorted square-planar with the chloride and 2,3-dihydro-1,2,4-oxadiazole ligands mutually trans, as the Pt atom lies on an inversion center. The 4-chlorobenzaldehyde molecules are statistically disordered about an inversion centre with equal occupancies for the two positions. The PtII complex forms a three-dimensional structure through C - H⋯Cl and weaker C - H⋯O interactions with the 4-chlorobenzaldehyde molecule.

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Kritchenkov, A. S., Gurzhiy, V. V., Bokach, N. A., & Kalibabchuk, V. A. (2013). Dichloridobis[3-(4-chlorophenyl)-2,N,N-trimethyl-2,3-dihydro-1,2, 4-oxadiazole-5-amine-κN 4]platinum(II)-4-chlorobenzaldehyde (1/1). Acta Crystallographica Section E: Structure Reports Online, 69(8). https://doi.org/10.1107/S1600536813017376

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