Abstract
The structure of polycrystalline strontium barium niobate at room temperature was refined by the Rietveld method. Sintered ceramic samples were used to collect powder neutron and X-ray diffraction data. The ratio Sr/Ba ~ 64/36 was found from the initial batch composition Sr0.61Ba0.39Nb2O6, corroborating with the quantitative X-ray dispersive spectroscopy (EDS) measurements. The structure is tetragonal with cell parameters a, b = 12.4504(3) Å and c = 3.9325(1) Å and space group P4bm. It was not necessary to introduce any positional disorder for the oxygen atoms. Cation Nb+5 displacements not parallel to the c direction are presented, which can influence the behavior of the ferroelectric properties.
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CITATION STYLE
Carrio, J. G., Mascarenhas, Y. P., Yelon, W., Santos, I. A., Garcia, D., & Eiras, J. A. (2002). Structure Refinement of (Sr,Ba)Nb2O6 Ceramic Powder from Neutron and X-Rays Diffraction Data. Materials Research, 5(1), 57–62. https://doi.org/10.1590/s1516-14392002000100010
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