Metal-mediated self-assembly of isocyanides and methyl 4-aminopyrimidine-5-carboxylate leads to luminescent PdII and PtII complexes featuring C,N-cyclometalated acyclic diaminocarbene (ADC) ligands. The solid-state luminescent properties of these diaminocarbene derivatives are attributed to their triplet-state metal/metal-to-ligand charge-transfer (3MMLCT) nature, which is driven by attractive intermolecular M···M interactions further reinforced by the intramolecular π-π interactions even in the structure of the Pd compound, which is the first Pd-ADC phosphor reported.
CITATION STYLE
Kashina, M. V., Luzyanin, K. V., Dar’in, D. V., Bezzubov, S. I., & Kinzhalov, M. A. (2024). Phosphorescent Cyclometalated Palladium(II) and Platinum(II) Complexes Derived from Diaminocarbene Precursors. Inorganic Chemistry, 63(12), 5315–5319. https://doi.org/10.1021/acs.inorgchem.3c03346
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