The carbon-Ferrier rearrangement: An approach towards the synthesis of C-glycosides

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Abstract

The carbon-Ferrier rearrangement is the reaction of appropriately functionalised glycals, with a variety of carbon nucleophiles such as allyltrimethylsilanes, alkynyltrimethylsilanes, silyl cyanides etc. involving the corresponding nucleophilic addition at the anomeric carbon with concomitant loss of a substituent at C-3. This leads to double bond migration to give 2,3-unsaturated sugars which act as useful chiral substrates for further manipulations in organic synthesis.

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Ansari, A. A., Lahiri, R., & Vankar, Y. D. (2013). The carbon-Ferrier rearrangement: An approach towards the synthesis of C-glycosides. Arkivoc, 2013(2), 316–362. https://doi.org/10.3998/ark.5550190.0014.223

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