Acesulfame k photodegradation over nitrogen-doped tio2

Abstract

Acesulfame K is a zero-calorie alternative to sugar used worldwide. There is contradictory information on the toxicity of the compound, but its accumulation in the aquatic environment is undeniable. In this study, one-pot sol-gel synthesis was used to obtain nitrogen-doped TiO2 photo-catalysts. Doping up to 6.29 wt % of nitrogen caused an increase in the surface area of the catalysts (48.55–58.23 m2·g−1) and a reduction of the pHPZC value (5.72–5.05). Acesulfame K photodegrada-tion was tested at the initial concentration of 20–100 ppm and the catalyst concentration at the level of 1 g·L−1. Compared to the pure anatase, 4.83–6.29 wt % nitrogen-doped TiO2 showed an effective photodegradation of Acesulfame K. Ninety percent molecule removal was obtained after ~100 min, ~90 min, and ~80 min for initial concentrations of 20 ppm, 50 ppm, and 100 ppm, respectively. The increased activity of the catalysts is due to the modification of the TiO2 lattice structure and probably the limitation of the photogenerated electron/hole charge carrier recombination. It was shown that the electrostatic interactions between Acesulfame K and the catalyst surface play an important role in the photodegradation efficiency.