Ni(II), Pd(II), and Cu(II) complexes of N-confused porphyrin (NCP) exhibit anion binding properties through a hydrogen bonding interaction at the peripheral NH of confused pyrrole ring. The binding constants of the tetrakis(pentafluorophenyl)-NCP metal complexes (1-M, M = Ni, Pd, Cu) for various halide anions in CH 2C1 2 increase in the order of F - > Cl - > I -, respectively. Zwitterionic resonance form of the NCP complexes as well as interactions between halide anions and a pentafluorophenyl group are suggested to be important for efficient anion binding.
CITATION STYLE
Maeda, H., Osuka, A., & Furuta, H. (2004). Anion binding properties of N-confused porphyrins at the peripheral nitrogen. In Journal of Inclusion Phenomena (Vol. 49, pp. 33–36). https://doi.org/10.1023/B:JIPH.0000031110.42096.d3
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