Hydrogen Peroxide as a Green Oxidant for the Selective Catalytic Oxidation of Benzylic and Heterocyclic Alcohols in Different Media: An Overview

Abstract

Among a plethora of known and established oxidant in organic chemistry, hydrogen peroxide stands in a special position. It is commercially and inexpensively available, highly effective, selective, and more importantly it is compatible with current environmental concerns, dictated by principles of green chemistry. Several chemicals or their intermediates that are important in our daily life such as pharmaceuticals, flavors, fragrances, etc. are products of oxidation of alcohols. In this review, we introduce hydrogen peroxide as an effective, selective, green and privileged oxidant for the catalyzed oxidation of primary and secondary benzylic and heterocyclic alcohols to corresponding carbonyl compounds in different media such as aqueous media, under solvent-free conditions, various organic solvent, and dual-phase system.