High-temperature reaction of sodium vapour with quartz glass

Abstract

Heat pipes are one of the most efficient ways to transfer thermal energy hundred times more efficiently than copper. In this work, we present the investigation of sodium terminal velocity inside a glass pulsating heat pipe. Velocity measurements were conducted under operating conditions within the range of 500-1 100 °C. Since sodium is generally able to etch glass and ceramic materials, its presence resulted in glass reduction and sodium oxidation. From the XPS analysis of specimens extracted from a glass pipe after sodium explosion, it can be concluded that the reaction products are sodium oxide Na2O and a thin layer of carbon, which is localized on the SiO2 glass. The character of damage induced by chemical reactions is analysed in this manuscript.