5-[(E)-2-Bromobenzylidene]-8-(2-bromo-phenyl)-2-hydroxy-10-methyl-3, 10-diaza-hexacyclo-[10.7.1.13,7.02,11.0 7,11.016,20]henicosa-1(20),12,14,16,18-pentaen-6-one

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Abstract

In the title compound, C33H26Br2N2O 2, the piperidine group adopts an envelope conformation while the two pyrrolidine groups adopt half-chair and envelope conformations. The dihydroacenaphthylene group is almost planar, with a maximum deviation of 0.105 (1) Å. The dihedral angle between the two bromophenyl rings is 60.19 (8)°. An intramolecular O-H⋯N interaction is observed, generating an S(5) ring motif. The crystal structure is stabilized by intermolecular C-H⋯O interactions. Short Br⋯Br [3.461 (1) Å] and Br⋯C [3.322 (2) Å] intermolecular contacts are observed, as well as π-π interactions [centroid-centroid distance = 3.793 (1) Å].

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Kumar, R. S., Osman, H., Ali, M. A., Rosli, M. M., & Fun, H. K. (2010). 5-[(E)-2-Bromobenzylidene]-8-(2-bromo-phenyl)-2-hydroxy-10-methyl-3, 10-diaza-hexacyclo-[10.7.1.13,7.02,11.0 7,11.016,20]henicosa-1(20),12,14,16,18-pentaen-6-one. Acta Crystallographica Section E: Structure Reports Online, 66(9). https://doi.org/10.1107/S1600536810033295

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