Reactions of vicinal aliphatic bis(hydroxylamines) with trifunctionalized methane derivatives

Abstract

The reactions of cis-1,2-bis(hydroxylamino)cyclohexane and 2,3-bis(hydroxylamino)-2,3-dimethylbutane with polyelectrophilic carbonyl compounds in ethanol were studied. It has been shown that such reactions result in the formation of predominantly five-membered heterocyclic rings with one or two nitrogen atoms. A nitronylnitroxide radical of 2-imidazoline type bearing a 1,3-dicarbonyl function was synthesized. © ARKAT-USA, Inc.