Photomagnetism in 5 nm nanocrystals of the alkali cation free-CoFe Prussian blue analogue embedded in a silica matrix

  • Bleuzen A
  • Goncalves M
  • Altenschmidt L
  • et al.
N/ACitations
Citations of this article
9Readers
Mendeley users who have this article in their library.

Abstract

5 nm nanocrystals of CoFe Prussian blue analogue totally exempt from any alkali cation were prepared. Their photomagnetic properties were compared to those of the corresponding powder made of 150 nm particles as well as to those of 5 nm nanocrystals of CoFe PBAs embedded in comparable silica matrices, made of CoIIFeIII pairs and prepared under various conditions. The photomagnetic investigation of the nanoparticles exempt of any alkali cation clearly shows that they are transformed by light and the comparison of their photomagnetic properties to those of the powder made of particles of bigger size with the same chemical composition suggests that the species involved in the switching properties are surface species. Furthermore, the comparison of the magnetic properties of nanoparticles prepared under various conditions also suggests that the aggregation state of the nanoparticles in the porous channels of the silica matrix, by modulating inter-particle interactions, plays a predominant role in the magnetic properties of the nanoparticles assemblies.

Cite

CITATION STYLE

APA

Bleuzen, A., Goncalves, M., Altenschmidt, L., Fornasieri, G., Bordage, A., & Rivière, E. (2020). Photomagnetism in 5 nm nanocrystals of the alkali cation free-CoFe Prussian blue analogue embedded in a silica matrix. Chemistry Squared, 4, 1. https://doi.org/10.28954/2020.csq.03.001

Register to see more suggestions

Mendeley helps you to discover research relevant for your work.

Already have an account?

Save time finding and organizing research with Mendeley

Sign up for free