Ten-lump kinetic model for the two-stage riser catalytic cracking for maximizing propylene yield (TMP) process

Abstract

Modeling Fluid Catalytic Cracking (FCC) riser reactors is of significance to FCC unit control, optimization and failure detection, as well as the development and design of new riser reactors. Under the guidance of catalytic reaction mechanisms and the demands for commercial production, a ten-lump kinetic model was developed for the TMP process in this study. The feedstock and products were divided into ten lumps by reasonably simplifying the reaction network, including heavy oil, diesel oil, gasoline olefins, gasoline aromatics, gasoline saturates, (butane ? propane), butylene, propylene, dry gas and coke. Thirty-five sets of model parameters were estimated with the combined simulated annealing method and the damped least square method. The findings indicated that the model could predict the riser key products and their compositions quite well; thereby it could be useful to the production practice for the TMP process.