1,3-Diiodobenzene on Cu(111)-an exceptional case of on-surface Ullmann coupling

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Abstract

Ullmann coupling of 1,3-diiodobenzene is studied on Cu(111) surfaces in ultra-high vacuum (UHV). In situ Scanning Tunneling Microscopy (STM) at room temperature revealed an unexpected ordered arrangement of highly uniform reaction products adsorbed atop a closed iodine monolayer.

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Rastgoo Lahrood, A., Björk, J., Heckl, W. M., & Lackinger, M. (2015). 1,3-Diiodobenzene on Cu(111)-an exceptional case of on-surface Ullmann coupling. Chemical Communications, 51(68), 13301–13304. https://doi.org/10.1039/c5cc04453g

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