Synthesis of new pentacyclo[5.4.0.0 2,6.0 3,10.0 5,9]undecane-8,11- dione (PCU) cyanosilylated derivatives using sulphated zirconia and hydrotalcite as catalysts in microwave-assisted reactions under solvent free conditions

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Abstract

A comparison was made of the effectiveness of the functionalization reactions of pentacyclo[5.4.0.0 2,6.0 3,10.0 5,9]undecane-8,11-dione (PCU) using sulphated zirconia in protection-deprotection reactions and Mg/Al hydrotalcite in a cyanosilylation reaction, under classical thermal conditions and imposing microwave radiation; improved yields and reaction times were considered.

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Guerra-Navarro, N. A., Palacios-Grijalva, L. N., Angeles-Beltrán, D., Negrón-Silva, G. E., Lomas-Romero, L., González-Zamora, E., … Navarrete-Bolaños, J. (2011). Synthesis of new pentacyclo[5.4.0.0 2,6.0 3,10.0 5,9]undecane-8,11- dione (PCU) cyanosilylated derivatives using sulphated zirconia and hydrotalcite as catalysts in microwave-assisted reactions under solvent free conditions. Molecules, 16(8), 6561–6576. https://doi.org/10.3390/molecules16086561

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