Modular Synthesis of a Dual Metal–Dual Semiconductor Nano‐Heterostructure

Abstract

Reported is the design and modular synthesis of a dual metal–dual semiconductor heterostructure with control over the dimensions and placement of its individual components. Analogous to molecular synthesis, colloidal synthesis is now evolving into a series of sequential synthetic procedures with separately optimized steps. We detail the challenges and parameters that must be considered when assembling such a multicomponent nanoparticle, and their solutions. This multicomponent nanosystem, Ru‐CdSe@CdS‐Pt, was designed to achieve charge carrier separation and directional transfer across different interfaces toward two separate redox catalysts. This heterostructure may potentially serve as a nanometric closed circuit photoelectrochemical cell.